Product ID:ETHANOL 200 PROOF
MSDS Date:03/01/1997
FSC:6810
NIIN:00-823-8003
Status Code:A
MSDS Number: CKPFC

Emergency Phone: 203-740-3471

Info Phone: 800-424-9300, 203-740-3471

Cage: 69267

Telephone: 203-740-3471

Cage: 69267

ETHANOL

CAS: 64-17-5

RTECS: KQ6300000

OSHA PEL 1900 MG/M3;1000 PPM

ACGIH TLV: 1880 MG/M3;1000 PPM

LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Health Hazards Acute and Chronic:SWALLOWING: MAY CAUSE DIZZINESS,
FAINTNESS, DROWSINESS, DECREASED AWARENESS OR RESPONSIVENESS,
NAUSEA, VOMITING, STAGGERING GAIT, LACK OF COORDINATION, AND COMA.
SKIN: NO HARMFUL EFFECTS ON NORMAL SKI N. INHALATION: HIGH VAPOR
CONCENTRATION MAY CAUSE BURNING SENSATION IN NOSE AND THROAT AND
STINGING AND WATERING IN THE EYES. AT CONCENTRATIONS WHICH CAUSE
IRRITATION, DIZZINESS, FAINTNESS, DROWSINESS , NAUSEA AND VOMITING
MAY ALSO OCCUR. SKIN: NO EVIDENCE OF HARMFUL EFFECTS FROM AVAILABLE
INFORMATION. EYE: MAY CAUSE IRRITATION INCLUDING STINGING, TEARING,
AND REDNESS.
Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Effects of Overexposure:SWALLOWING: MAY CAUSE DIZZINESS, FAINTNESS,
DROWSINESS, DECREASED AWARENESS OR RESPONSIVENESS, NAUSEA,
VOMITING, STAGGERING GAIT, LACK OF COORDINATION, AND COMA. SKIN: NO
HARMFUL EFFECTS ON NORMAL SKI N. INHALATION: HIGH VAPOR
CONCENTRATION MAY CAUSE BURNING SENSATION IN NOSE AND THROAT AND
STINGING AND WATERING IN THE EYES. AT CONCENTRATIONS WHICH CAUSE
IRRITATION, DIZZINESS, FAINTNESS, DROWSINESS , NAUSEA AND VOMITING
MAY ALSO OCCUR. SKIN: NO EVIDENCE OF HARMFUL EFFECTS FROM AVAILABLE
INFORMATION. EYE: MAY CAUSE IRRITATION INCLUDING STINGING, TEARING,
AND REDNESS.
Medical Cond Aggravated by Exposure:REPEATED EXPOSURE TO ETHANOL MAY
AGGRAVATE LIVER INJURY PRODUCED FROM OTHER CAUSES.

First Aid:OBTAIN MEDICAL ATTENTION FOR ALL CASES OF OVEREXPOSURE.
SWALLOWING: IF PATIENT IS FULLY CONSCIOUS, GIVE TWO GLASSES OF
WATER. INDUCE VOMITING. SKIN: WASH SKIN WITH SOAP AND WATER FOR AT
LEAST 15 MINU TES. INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF NOT BREATHING. IF BREATHING IS DIFFICULT OXYGEN MAY
BE GIVEN BY QUALIFIED PERSONNEL; OBTAIN MEDIAL ASSISTANCE IF
DISCOMFORT PERSIST S. EYE: FLUSH EYES WITH WATER FOR AT LEAST 15
MINUTES. NOTE TO PHYSICIAN:SYMPTOMS VARY WITH ALCOHOL LEVEL OF THE
BLOOD. MILD ALCOHOL INTOXICATION OCCURS AT BLOOD LEVELS BETWEEN
0.5-1.5%

Flash Point Method:TCC
Flash Point:=14.4C, 58.F
Lower Limits:3.3
Upper Limits:19.0
Extinguishing Media:APPLY ALCOHOL-TYPE OR ALL PURPOSE FOAM BY
MANUFACTURER'S RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE CARBON
DIOXIDE OR DRY CHEMICAL MEDIA FOR SMALL FIRES.
Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS AND STRUCTURES; USE WATER SPRAY TO DISPERSE
VAPORS-RE-IGNITION IS POSSIBLE; USE SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO SOURCE OF IGNITION
AND FLASH BACK. VAPORS MAY SETTLE IN LOW OR CONFINED SPACES. MAY
PRODUCE A FLOATING FIRE HAZARD. STATIC IGNITION HAZARD CAN RESULT
FROM HANDLING AND USE.

Spill Release Procedures:SMALL SPILLS CAN BE FLUSHED WITH LARGE AMOUNTS
OF WATER. LARGE SPILLS: ELIMINATE ALL IGNITION SOURCES, GROUND ALL
EQUIPMENT; DO NOT WALK THROUGH SPILL; STOP SPILL IF POSSIBLE;
PREVENT ENTRY INTO SEWER S, CONFINED SPACES, ETC., USE A VAPOR
SUPPRESSING FOAM TO REDUCE VAPORS; ABSORB SPILL WITH
NON-COMBUSTIBLE MATTER AND TRANSFER TO CONTAINERS; USE NON-SPARKING
TOOLS TO COLLECT ABSORBED MATERIALS.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Handling and Storage Precautions:FLAMMABLE MATERIAL-KEEP AWAY FROM
HEAT, SPARKS, AND FLAME; SUDDEN RELEASES OF HOT ORGANIC VAPORS OR
MISTS FROM PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURE MAY
RESULT IN IGNITIONS WITHOUT THE P RESENCE OF OBVIOUS IGNITION
SOURCES. GROUND CONTAINER WHEN TRANSFERRING PRODUCT.
Other Precautions:AVOID CONTACT WITH EYES. KEEP CONTAINER CLOSED. USE
WITH ADEQUATE VENTILATION. VAPORS MAY COLLECT IN CONTAINER; TREAT
EMPTY CONTAINERS AS HAZARDOUS. WASH THOROUGHLY AFTER HANDLING.
VAPORS MAY SETTLE I N LOW OR CONFINED AREAS.

Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS IN HIGH
VAPOR CONCENTRATION.
Ventilation:SPECIAL, LOCAL VENTILATION IS NEEDED WHERE VAPORS ESCAPE TO
THE WORKPLACE AIR.
Protective Gloves:YES
Eye Protection:SAFETY GLASSES
Other Protective Equipment:LAB COAT OR UNIFORM, EYE WASH, SAFETY
SHOWER.
Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Supplemental Safety and Health
SYNONYMS: ETHYL ALCOHOL ABSOLUTE, DEHYDRATE ETHANIL; ANHYDROUS ETHANOL,
METHYLATED SPIRITS.

HCC:F2
Boiling Pt:=78.3C, 172.9F
B.P. Text:@760MMHG
Melt/Freeze Pt:=-114.1C, -173.2F
Vapor Pres:44.6 MMHG@20C
Vapor Density:1.6 (AIR=1
Spec Gravity:.7906@20/20C
VOC Pounds/Gallon:790
Evaporation Rate & Reference:3.3 (BUAC=1)
Solubility in Water:100%@20C
Appearance and Odor:CLEAR, COLORLESS LIQUID; CHARACTERISTIC ODOR
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS; STRONG INORGANIC ACIDS
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:CARBON MONOXIDE AND/OR CARBON DIOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF SPILL-CLEAN UP AND OTHER WASTES IN
ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS. VAPORS MAY
COLLECT IN EMPTY CONTAINERS. TREAT EMPTY CONTAINERS AS HAZARDOUS.

Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY.

Transport Information:US DOT PROPER SHIPPING NAME: ETHYL ALCOHOL.
HAZARD CLASS: 3. UN NUMBER: 1170. IMO INFORMATION: ETHANOL OR
ETHANOL SOLUTIONS. LABEL OF CLASS: 3. PACKING GROUP: II.
INTERMEDIATE FLASHPOINT GROUP.

SARA Title III Information:SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
OF 1986 (SARA) TITLE III REQUIRES EMERGENCY PLANNING BASED ON
HRESHOLD PLANNING QUANTITIES AND RELEASE REPORTING BASED ON
REPORTABLE AMOUNTS (40 CFR 355 [ USED FOR SARA 302, 3044, 311,
312]) COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL WHICH COULD
REQUIRE REPORTING UNDER THIS STAUTE ARE: NONE. SUPERFUND AMENDMENTS
AND REAUTHORIZATION ACT OF 1986 (SARA) TITLE III REQUIRES
SUBMISSION OF ANNUAL REPORTS OF RELEASE OF TOXIC CHEMICALS THAT
APPEAR IN 40 CFR 372 (FOR SARA 313). THIS INFORMATION MUST BE
INCLUDED IN ALL MSDS'S. COMPONENTS PRESENT AT A REPOR TABLE LEVEL:
NONE.
Federal Regulatory Information:CERCLA REQUIRS NOTIFICATION OF THE
NATIONAL RESPONSE CENTER OF RELEASE OF QUANTITIES OF HAZARDOUS
SUBSTANCES EQUAL TO OR GREATER THAN THE REPORTABLE QUANTITIES (RQS)
IN CFR. COMPONENTS PRESENT IN THIS PRODUCT AT A LEVEL WHICH COULD
REQUIRE REPORTING UNDER THIS PRODUCT AT A LEVEL WHICH COULD REQUIRE
REPORTING UNDER THIS STAUTE: ACETONE, CAS# 67-64-1, 0.0002%;
METHANOL, CAS# 67-56-1, 0.0150%; ACETAL DEHYDE, CAS# 75-07-0,
0.0020 %. TSCA: THE INGREDIENTS OF THIS PRODUCT ARE ON THE TSCA
INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THIS PRODUCT
CONTAINS TRACE LEVELS OF ACETALDEHYDE KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. MASSACHUSETTS: HAZARDOUS SUBSTANCES AND
EXTREMELY HAZARDOUS SUBSTANCES M UST BE IDENTIFIED. COMPONENTS
WHICH MAY REQUIRE REPORTING: EXTREMELY HAZARDOUS: ACETALDEHYDE
(CAS# 75-07-0), <0.0020%; HAZARDOUS: ETHANOL (CAS# 64-17-5), 100 %.
PENNSYLVANIA: HAZARDOUS SUBSTANCES MUST BE IDENTIFIED: HAZARDOUS:
ETHANOL (CAS# 64-17-5) 100%.